Friday, January 11, 2008

FUEL

Fuels used include petroleum spirit (North American term: gasoline, British term: petrol), autogas (liquified petroleum gas), compressed natural gas, hydrogen, diesel fuel, jet fuel, landfill gas, biodiesel, biobutanol, peanut oil and other vegoils, bioethanol, biomethanol (methyl or wood alcohol) and other biofuels. Even fluidised metal powders and explosives have seen some use. Engines that use gases for fuel are called gas engines and those that use liquid hydrocarbons are called oil engines. However, gasoline engines are also often colloquially referred to as 'gas engines'.
The main limitations on fuels are that it must be easily transportable through the fuel system to the combustion chamber, and that the fuel release sufficient energy in the form of heat upon combustion to make use of the engine practical.
The oxidiser is typically air, and has the advantage of not being stored within the vehicle, increasing the power-to-weight ratio. Air can, however, be compressed and carried aboard a vehicle. Some submarines are designed to carry pure oxygen or hydrogen peroxide so that they do not need air from the atmosphere. Some race cars carry nitrous oxide as oxidizer. Other chemicals such as chlorine or fluorine have been used experimentally, but have not been found to be practical.
Diesel engines are generally heavier, noisier and more powerful at lower speeds than gasoline engines. They are also more fuel-efficient in most circumstances and are used in heavy road vehicles, some automobiles (increasingly so for their increased fuel efficiency over gasoline engines), ships, railway locomotives, and light aircraft. Gasoline engines are used in most other road vehicles including most cars, motorcycles and mopeds. Note that in Europe, sophisticated diesel-engined cars have taken over about 40% of the market since the 1990s. There are also engines that run on hydrogen, methanol, ethanol, liquefied petroleum gas (LPG) and biodiesel. Paraffin and tractor vaporising oil (TVO) engines are no longer seen.

HYDROGEN ENGINE

Some have theorized that in the future hydrogen might replace such fuels. Furthermore, with the introduction of hydrogen fuel cell technology, the use of internal combustion engines may be phased out. The advantage of hydrogen is that its combustion produces only water. This is unlike the combustion of fossil fuels, which produce carbon dioxide, a known green house gas GHG, carbon monoxide resulting from incomplete combustion, and other local and atmospheric pollutants such as sulfur dioxide and nitrogen oxides that lead to urban respiratory problems, acid rain, and ozone gas problems. However, free hydrogen for fuel does not occur naturally, burning it liberates less energy than it takes to produce hydrogen in the first place due to the second law of thermodynamics.
Although there are multiple ways of producing free hydrogen, those require converting combustible molecules into hydrogen, so hydrogen does not solve any energy crisis, moreover, it only addresses the issue of portability and some pollution issues. The disadvantage of hydrogen in many situations is its storage. Liquid hydrogen has extremely low density- 14 times lower than water and requires extensive insulation, whilst gaseous hydrogen requires heavy tankage. Although hydrogen has a higher specific energy, the volumetric energetic storage is still roughly five times lower than petrol, even when liquified. (The 'Hydrogen on Demand' process, designed by Steven Amendola, creates hydrogen as it is needed, but has other issues, such as the high price of the sodium borohydride, the raw material. Sodium borohydride is renewable and could become cheaper if more widely produced.)