HYDROGEN ENGINE

Some have theorized that in the future hydrogen might replace such fuels. Furthermore, with the introduction of hydrogen fuel cell technology, the use of internal combustion engines may be phased out. The advantage of hydrogen is that its combustion produces only water. This is unlike the combustion of fossil fuels, which produce carbon dioxide, a known green house gas GHG, carbon monoxide resulting from incomplete combustion, and other local and atmospheric pollutants such as sulfur dioxide and nitrogen oxides that lead to urban respiratory problems, acid rain, and ozone gas problems. However, free hydrogen for fuel does not occur naturally, burning it liberates less energy than it takes to produce hydrogen in the first place due to the second law of thermodynamics.
Although there are multiple ways of producing free hydrogen, those require converting combustible molecules into hydrogen, so hydrogen does not solve any energy crisis, moreover, it only addresses the issue of portability and some pollution issues. The disadvantage of hydrogen in many situations is its storage. Liquid hydrogen has extremely low density- 14 times lower than water and requires extensive insulation, whilst gaseous hydrogen requires heavy tankage. Although hydrogen has a higher specific energy, the volumetric energetic storage is still roughly five times lower than petrol, even when liquified. (The 'Hydrogen on Demand' process, designed by Steven Amendola, creates hydrogen as it is needed, but has other issues, such as the high price of the sodium borohydride, the raw material. Sodium borohydride is renewable and could become cheaper if more widely produced.)

Once ignited and burnt, the combustion products, hot gases, have more available energy than the original compressed fuel/air mixture (which had higher chemical energy). The available energy is manifested as high temperature and pressure which can be translated into work by the engine. In a reciprocating engine, the high pressure product gases inside the cylinders drive the engine's pistons.
Once the available energy has been removed, the remaining hot gases are vented (often by opening a valve or exposing the exhaust outlet) and this allows the piston to return to its previous position (Top Dead Center - TDC). The piston can then proceed to the next phase of its cycle, which varies between engines. Any heat not translated into work is normally considered a waste product, and is removed from the engine either by an air or liquid cooling system.
Exhaust gas is flue gas which occurs as a result of the combustion of fuels such as natural gas, gasoline/petrol, diesel, fuel oil or coal. It is discharged into the atmosphere through an exhaust pipe or flue gas stack.
Although the largest part, by far, of most combustion gases is relatively harmless nitrogen (N2) and carbon dioxide (CO2), a relatively very small part of it is undesirable noxious or toxic substances, such as carbon monoxide (CO), hydrocarbons, nitrogen oxides (NOx), and particulate matter. When a hydrocarbon combusts, it also produces water, or H2O
Exhaust gas from an industrial plantEmission standards focus on reducing pollutants contained in the exhaust gases from vehicles as well as from industrial flue gas stacks and other air pollution exhaust sources in various large-scale industrial facilities such as petroleum refineries, natural gas processing plants, petrochemical plants and chemical production plants.
In steam engine terminology the exhaust is steam that no longer has the capacity to do useful work, i.e. literally exhausted.